{"id":494,"date":"2021-05-15T08:06:00","date_gmt":"2021-05-15T06:06:00","guid":{"rendered":"http:\/\/upturn.site\/pl\/?p=494"},"modified":"2023-04-06T13:02:33","modified_gmt":"2023-04-06T11:02:33","slug":"publikacja-w-applied-surface-science","status":"publish","type":"post","link":"https:\/\/upturn.site\/pl\/publikacja-w-applied-surface-science\/","title":{"rendered":"Publikacja w Applied Surface Science"},"content":{"rendered":"\n<h4 class=\"wp-block-heading has-theme-palette-8-background-color has-background\">Development of novel (BiO) 2OHCl\/BiOBr enriched with boron doped-carbon nanowalls for photocatalytic cytostatic drug degradation: assessing photocatalytic process utilization in environmental condition.<\/h4>\n\n\n\n<div style=\"height:30px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<h5 class=\"wp-block-heading\"><strong>Abstrakt<\/strong><\/h5>\n\n\n\n<p>In this work, a series of novel (BiO)2OHCl\/BiOBr-x%B:DGNW (x = 0%, 1%, 1.5%, 2%) composites with different content of boron-doped diamond\/graphene nanowalls (B:DGNW) were fabricated by simple solvothermal synthesis. A boron-doped diamond\/graphene nanowalls (B:DGNW) were prepared by CVD method. A series of analyses: XRD, XPS, SEM, and TEM showed that the photocatalyst (BiO)2OHCl\/BiOBr-x%B:DGNW with a \u201cflower-like\u201d morphology was successfully synthesized. The photocatalytic activity of the obtained composites in the degradation of 5-fluorouracil (5-FU) in various water matrices (deionized water, sea, and surface water) under the influence of artificial solar radiation was assessed. The results showed that all the prepared (BiO)2OHCl\/BiOBr-x%B:DGNW composites were characterized by excellent photocatalytic activity. The calculated pseudo-first rate constant for 5-FU degradation increased with the elevation of amount of B:DGNW up to 1.5% in (BiO)2OHCl\/BiOBr, and it dropped down to value obtained for non-riched material by B:DGNW, when of 2% B:DGNW was introduced to composite. The results showed that B:DGNW play a key role in the separation of charge carriers h+\/e- enhancing degradation rate of 5-FU. The photoactivity of (BiO)2OHCl\/BiOBr-1.5%B:DGNW composite to 5-FU removal was also satisfied in natural water, although its structure has changed in seawater.<\/p>\n\n\n\n<div style=\"height:30px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/upturn.site\/upturn_klon\/wp-content\/uploads\/2022\/10\/03-1024x498.jpg\" alt=\"\" class=\"wp-image-456\"\/><\/figure>\n\n\n\n<p><a href=\"https:\/\/doi.org\/10.1016\/j.apsusc.2022.152664\">Pe\u0142na tre\u015b\u0107<\/a><\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n","protected":false},"excerpt":{"rendered":"<p>Development of novel (BiO) 2OHCl\/BiOBr enriched with boron doped-carbon nanowalls for photocatalytic cytostatic drug degradation: assessing photocatalytic process utilization in environmental condition.<\/p>\n","protected":false},"author":1,"featured_media":495,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_kad_post_transparent":"","_kad_post_title":"","_kad_post_layout":"","_kad_post_sidebar_id":"","_kad_post_content_style":"","_kad_post_vertical_padding":"","_kad_post_feature":"","_kad_post_feature_position":"","_kad_post_header":false,"_kad_post_footer":false,"footnotes":""},"categories":[12],"tags":[],"_links":{"self":[{"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/posts\/494"}],"collection":[{"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/comments?post=494"}],"version-history":[{"count":6,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/posts\/494\/revisions"}],"predecessor-version":[{"id":533,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/posts\/494\/revisions\/533"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/media\/495"}],"wp:attachment":[{"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/media?parent=494"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/categories?post=494"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/upturn.site\/pl\/wp-json\/wp\/v2\/tags?post=494"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}